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Silicate weathering and organic carbon (OC) burial in soil regulate atmospheric CO2, but their influence on each other remains unclear. Generally, OC oxidation can generate acids that drive silicate weathering, yet clay minerals that form during weathering can protect OC and limit oxidation. This poses a conundrum where clay formation and OC preservation either compete or cooperate. Debate remains about their relative contributions because quantitative tools to simultaneously probe these processes are lacking while those that exist are often not measured in concert. Here we demonstrate that Li isotope ratios of sediment, commonly used to trace clay formation, can help constrain OC cycling. Measurements of river suspended sediment from two watersheds of varying physiography and analysis of published data from Hawaii soil profiles show negative correlations between solid-phase d7Li values and OC content, indicating the association of clay mineral formation with OC accumulation. Yet, the localities differ in their ranges of d7Li values and OC contents, which we interpret with a model of soil formation. We find that temporal trends of Li isotopes and OC are most sensitive to mineral dissolution/clay formation rates, where higher rates yield greater OC stocks and lower d7Li values. Whereas OC-enhanced dissolution primarily dictates turnover times of OC and silicate minerals, clay protection distinctly modifies soil formation pathways and is likely required to explain the range of observations. These findings underscore clay mineral formation, driven primarily by bedrock chemistry and secondarily by climate, as a principal modulator of weathering fluxes and OC accumulation in soil. 

Ice cores and offshore sedimentary records demonstrate enhanced ice loss along Antarctic coastal margins during millennial-scale warm intervals within the last glacial termination. However, the distal location and short temporal coverage of these records leads to uncertainty in both the spatial footprint of ice loss, and whether millennial-scale ice response occurs outside of glacial terminations. Here we present a >100kyr archive of periodic transitions in subglacial precipitate mineralogy that are synchronous with Late Pleistocene millennial-scale climate cycles. Geochemical and geochronologic data provide evidence for opal formation during cold periods via cryoconcentration of subglacial brine, and calcite formation during warm periods through the addition of subglacial meltwater originating from the ice sheet interior. These freeze-flush cycles represent cyclic changes in subglacial hydrologic-connectivity driven by ice sheet velocity fluctuations. Our findings imply that oscillating Southern Ocean temperatures drive a dynamic response in the Antarctic ice sheet on millennial timescales, regardless of the background climate state.

 

High‐latitude glacierized coastal catchments of the Gulf of Alaska (GoA) are undergoing rapid hydrologic changes in response to climate change and glacial recession. These catchments deliver important nutrients in the form of both inorganic and organic matter to the nearshore marine environment, yet are relatively understudied with respect to characterization of the sediment and solute generation processes and total yields. Using multiple linear regression informed by Bayesian Information Criterion analysis we empirically demonstrate how watershed characteristics affect suspended sediment and solute generation as represented by concentration‐discharge relationships. We find that watershed mean slope and relief control solute generation and that solute yields are influenced most by glacier coverage. We contribute a new flux and concentration‐discharge based conceptualization for understanding solute cycles across a hydroclimatic gradient of GoA watersheds that can be used to better understand future watershed responses to rapid hydrologic change.

 

Terrestrial gradients in the oxygen isotopic composition of meteoric water (δ¹⁸O), as reconstructed through proxies, reflect characteristics of ancient hydrologic conditions. These gradients are primarily influenced by the atmospheric transport of water vapor and the balance of precipitation and evapotranspiration, which are linked to climate and topography. We incorporate these effects into a one‐dimensional model that predicts the spatial evolution ofδ¹⁸Obased on local topography and the regional water‐energy budget. Specifically, we build on existing reactive transport models by incorporating parameterizations of orographic precipitation and energetic constraints on evapotranspiration following the Budyko water balance framework. We test our model on three modern transects that represent topographically distinct environments. These are the Amazon Basin (lowlands), the Cascade Range (mountains), and the eastern Himalayan Range (lowlands and mountains). Comparisons among these gradients demonstrate that the topographic regime determines how sensitive isotope records are to hydroclimate evolution. As a result, isotope records differentially express signatures of topography and the regional water balance, and we present a quantitative framework to predict this trade‐off. Finally, we link these effects to climate evolution and discuss how our model may help disentangle topographic and climatic signals through Earth history.